Gas monitor

ABSTRACT

Gas monitor based on tuneable diode laser spectroscopy comprising at least one light source (1000) matched to at least one target gas (5000) and at least one light sensitive detector (3000), and a mirror arrangement (2000) made of a central mirror (2100) directing a light beam (4100) from the light source (1000) through the target gas (5000) to be analysed as well as a surrounding mirror (2300) around the central mirror (2100) directing the light transmitted through the gas (5000) onto at least one detector (3000). The gas monitor also comprising a control system controlling light sources (1000, 1100, 1200), digitising analogue signals as well as determining characteristics of the gas (5000). The gas monitor further comprising internal alignment means for fine alignment. The gas monitor can comprise two or more light sources (1000, 1100, 1200) targeting gases with absorption lines in two or more wavelength ranges. The gas monitor can in certain embodiments comprise one or more gas cells (2910, 2920) that can be inserted in an optical path to verify the performance of the instrument.

BACKGROUND OF THE INVENTION Technical Field

The invention relates in general to monitoring of gases by opticalmeans. More specifically it relates to a gas monitor and method fordetermining characteristics of a target gas by directing light through asample of said gas.

Background of the Invention

In process manufacturing, the energy industry, and other industrialsettings there is a need to monitor the concentration, or pressure, ofvarious gases, e.g., for process control and for safety reasons. Gasmonitors based on tuneable diode lasers have gained market shares inrecent years owing to providing a robust measurement technique lessprone to interference from other gases, and capability to measurein-situ in high temperatures and under high pressures.

In a typical optical gas monitor, one single laser sensor can in generalonly measure one or two gases, possibly three in some cases, due tolimited wavelength tuning range and lack of suitable absorption linesclose to each other. This means that at least two lasers, and inpractice at least two gas monitoring instruments, are needed to measuretwo or more gases, and this could lead to multiple sets of holes in aduct or stack. In addition, the optical path might in general bedifficult to align, in particular in long open path applications. In atypical gas monitoring instrument for long open path applications, aNewtonian-type telescope might be used to direct the laser light towardsa retro-reflector, and then used to collect the reflected light to adetector. Alignment of such a gas monitoring instrument requires theentire telescope to be accurately directed towards the retro-reflector,which in general is cumbersome and time-consuming. In addition, thisarrangement has limited possibilities to cater for multiple lasers anddetectors along the beam path, as well as suffers from limited optionsin the positioning of the optical components. The use of multiple lasersand detectors in a single instrument can be realized by the use ofoptical fibres and couplers, but such components normally introducesignificant amounts of optical noise, which causes a degradation of theperformance of the measurement.

PRIOR ART

WO 2006/022550 A2 describes a gas monitor based on a tuneable lasersource that can be utilised with a retro-reflector to measure gasbetween the laser/detector and the retro-reflector.

DD 284527 A5 describes a device for infrared absorption measurementbased on a hybrid Newtonian-Cassegrain telescope, where an aperture ispresent in the centre of the main mirror, and a beamsplitting mirrorreplaces the normal diagonal secondary mirror of a Newtonian telescope.This device allows aligning a laser beam coaxially with the detectionpath, but the device is still limited by the need to align the entiretelescope, laser source, and detector towards the retro-reflector.

EP 2058671 A2 describes a device for laser range finding where a mirrorassembly is used consisting of a large concave mirror for collecting theback-scattered light, and a small flat part of the mirror is centered onthe large mirror, which is used to direct the laser beam coaxially withthe large mirror. However, this disclosure does not allow the lasersource and the detector to be positioned on separate optical axes, andthe device is not intended for gas measurements.

US 2005/0162655 A1 describes a device where two concave mirrors areused, the first mirror to direct light from an optical fibre towards theretro-reflector, and the second mirror to collect the reflected lightand direct it towards a second optical fibre connected to a detector.This disclosure requires the use of two concave mirrors, and theconstruction requires the entire device to be aligned towards theretro-reflector, including the light source fibre and the detectorfibre. It also uses optical fibres, which can introduce optical noise.

Due to these limitations of the techniques described in the art, newimproved apparatus and methods for gas monitoring would be advantageous.

DISCLOSURE OF THE INVENTION Problems to be Solved by the Invention

Therefore, a main objective of the present invention is to provide asystem and a method that overcomes the problems described above.

Accordingly, embodiments of the present disclosure preferably seek tomitigate, alleviate or eliminate one or more deficiencies, disadvantagesor issues in the art, such as the above-identified, singly or in anycombination by providing a device, system or method according to theappended patent claims for gas monitoring based on optical means.

The disclosure solves two common problems in gas monitoring based ontuneable diode laser spectroscopy. The first problem, i.e., alignment ofthe sensor, is solved by allowing alignment by moving only internalparts. The second problem, i.e., monitoring of more than one gas, issolved by utilising a plurality of tuneable diode lasers in one singleinstrument in one common optical path without using optical fibres andcouplers that are a source of optical noise.

Means for Solving the Problems

The objective is achieved according to the invention by a gas monitorsystem for determining at least one characteristic of a target gas asdefined in the preamble of claim 1, having the features of thecharacterising portion of claim 1 and a method for determining at leastone characteristic of a target gas as defined in the preamble of claim25, having the features of the characterising portion of claim 25.

SUMMARY OF THE INVENTION

A first object of the invention is to provide a gas monitor system fordetermining at least one characteristic of a target gas.

A further object of the invention is to provide a gas monitor systemwith an optimized number of components and relative positions of these.

One or more of these objects are being addressed by the presentinvention as defined by the accompanying claims.

According to a first aspect of the invention, there is provided a gasmonitor system for determining at least one characteristic of a targetgas, the gas monitor system comprising at least one light source, thelight source being arranged for emitting light in a wavelength rangewhere the target gas has at least one absorption line, the systemfurther comprising a retro reflector and a control unit, the gas monitorsystem being arranged for directing the light through the target gas tothe retro reflector returning the light to a receiving optics, thesystem further comprising a detector system with at least one lightsensitive detector for detecting the light, the detector arranged forproviding a signal to be received by the control unit, the control unitarranged for controlling the gas monitor system and calculating the atleast one characteristic of the gas, characterized by the gas monitorsystem comprising a mirror arrangement, the mirror arrangementcomprising a central mirror and a surrounding mirror each with a surfaceand an optical axis, where the central and the surrounding mirror arearranged with an offset angle between their optical axes, where theoptical axes of the central and the surrounding mirror intersect at anintersection point in the proximity of the geometrical center of thesurface of the central mirror, where the mirror arrangement can betilted in any direction within a 3-dimensional solid angle around apivot point, where the pivot point is located in the proximity of theintersection point, the central mirror being arranged for receivinglight from the light source and directing light to the retro reflector,the retro reflector arranged for returning the light to the surroundingmirror, the surrounding mirror arranged for reflecting the light intothe detector system.

The intersection point of the optical axes can preferably be locatedless than 10 mm from the geometrical center of the surface of thecentral mirror.

The pivot point can preferably be located less than 20 mm from theintersection point of the optical axes.

More preferably, the intersection point of the optical axes and thepivot point can be located at the geometrical center of the surface ofthe central mirror.

The gas monitor system may be arranged for forming beams, each beamhaving an axis, beam from the light source system comprising the lightsource to central mirror, beam from central mirror to retro reflector,beam from retro reflector to surrounding mirror and beam from surroundmirror to detector system, and where the gas monitor system is arrangedfor the beams to and from the retro reflector to be substantiallyco-axial, and the axes of the beams to the central mirror from the lightsource system and from the surrounding mirror to the detector system tobe non-coincident.

Twice the angle between the optical axis of the central mirror and thesurrounding mirror substantially may correspond to the angle between theoptical axis of the light source system and the detector system. Thelight source system and the detector system are positioned on differentoptical axes.

The central mirror and surrounding mirror may each comprise a surfacefor reflecting light, and the mirror arrangement is arranged such thatthe surface of the surrounding mirror surrounds the surface of thecentral mirror, where the surface of the surrounding mirror is largerthan the surface of the central mirror. The surfaces of the central andsurrounding mirror can further be arranged such that the intersectionspoint of the optical axis are located at in the optical center of thecentral mirror. The central mirror typically may be one of the followingforms: flat, parabolic, off-axis parabolic, and spherical, and thesurrounding mirror: flat, parabolic, off-axis parabolic and spherical.

The detector system may be located outside the beams between the mirrorarrangement and the retro reflector. The light source typically is alaser of one of the following types VCSEL lasers, DFB lasers, QCL andICL lasers, Fabry-Perot lasers, as well as different array types oflasers.

The retro reflector may be one of the following types: cube corner, areflective tape or any other device or surface capable of returning somelight to the instrument.

The mirror arrangement may be is arranged for pointing the beam from thecentral mirror in a pointing direction mainly towards the retroreflector, and where the gas monitor system comprises alignment meansfor adjusting the pointing direction of the mirror arrangement.

The alignment means may be arranged for providing tilting of the mirrorarrangement mainly around a pivot point. Further, the pivot point may belocated in the proximity of the center of the surface of the centralmirror, or behind said center in the proximity of the elongation of itsoptical axis.

The alignment means may comprise means for automatically aligning saidmirror assembly towards the retro reflector by moving said mirrorassembly while monitoring a signal, and finding an optimal signal.

The gas monitor system may comprise a visible light source arranged forsending a collimated beam of visible light substantially co-axially withthe beam from the at least one light source to facilitate alignment ofthe system.

Further, the system may comprise a plurality of light sources operatingat different wavelengths, each light source having a beam splitter formerging the light beams from the light sources to a common path; saidbeam splitters having spectral properties for the light from the lightsources corresponding to each beam splitter to be essentially reflected,while light at wavelengths from other light sources is essentiallytransmitted.

The gas monitor system may comprise a plurality of light sensitivedetectors and a plurality of beam splitters for separating thewavelengths from each light source to individual detectors, it may bearranged for time-multiplexing or a frequency-multiplexing to separatethe wavelengths from each light source.

The system may be arranged to let excess light from the beam splitterspass through at least one gas cell for each of the light sources andthen onto at least one additional light sensitive detector for each ofsaid light sources; said at least one gas cell containing gas withabsorption properties that suited to be used for self-calibration and tomonitor the instrument integrity with regards to spectral operationpoints.

Further the retro reflector may comprise a beam blocking plate arrangedsubstantially symmetrically around a center axis of the retro reflectorfor blocking light from being reflected by the retro reflector via thecentral mirror back to the light source, and the blocking plate maysubstantially be formed like a circular disc with a diameter optimizedfor a range of optical path length and beam divergence. Further, theblocking plate may be arranged in an angle tilted relative to theoptical axis of the retro reflector.

Further the retro reflector can comprise a central part wheresubstantially the reflective means have been removed to avoid laserlight being reflected back via the central mirror to the light source.

Still further, a diffuser element is placed in the central part of theretroreflector where the reflective means have been removed, thediffuser element reducing optical noise and reflections from surfacesbehind the retroreflector. The reflective surfaces of the central partcomprising a reflective surface which can be sand blasted or etched forsubstantially removing the reflective surface and making the diffuserelement.

A still further aspect of the invention is a method for determining atleast one characteristic of a target gas, comprising the followingsteps:

emitting light in a range where the target gas has at least oneabsorption line in a beam from a light source;reflecting the light by the central mirror through a sample of thetarget gas towards a retro reflector;returning the light by the retro reflector towards a surrounding mirrorsurrounding the central mirror;reflecting the light by the surrounding mirror towards a detectorsystem;detecting the light by at least one detector comprised by a detectorsystem;receiving a signal from the detector system and determining at least onecharacteristic of the gas by a control system.

The gas monitor typically is based on tuneable diode laser spectroscopycomprising at least one light source, where the light source typicallyis a tuneable laser matched to at least one target gas and at least onelight sensitive detector, and optical means to form light beams anddirect light beams through the target gas to be analysed as well asdirecting the light onto at least one detector. The gas monitor alsocomprising a control system controlling light sources, digitisinganalogue signals as well as determining characteristics of the gas. Thegas monitor further comprising internal alignment means for finealignment. The gas monitor can comprise two or more light sourcestargeting gases with absorption lines in two or more wavelength ranges.The gas monitor can in certain embodiments comprise one or more gascells that can be inserted in an optical path to verify the performanceof the instrument.

The disclosure comprises the combination of a mirror for the exitinglaser beam, and a larger mirror for collecting reflected light. FIG. 1depicts an example of a system where a moveable mirror assembly (2000)is used, comprising a concave mirror surface (2300), said concavesurface having a hole, in which an essentially flat mirror is mounted(2100). The mirror assembly can be tilted in all directions usingmechanics and motors or any other available actuators. The mirrorassembly is designed so that when the laser (1000) emits light (4100)this light reaches the flat mirror in the mirror assembly, the lightreflected (4200) from the flat mirror will reach the retro reflector(2200) and the light reflected (4300) from the retro reflector hits theconcave mirror (2300), the concave mirror focuses the light (4400) thatfinally reaches the detector (3000). As long as the instrument iscoarsely aligned and within the adjustable range the internal alignmentmeans will be able to align the instrument.

In addition to providing internal alignment of the instrument, thecurrent disclosure also enables multiple lasers to be included in thedesign following the same optical paths and utilizing the same alignmentmeans, as illustrated in the example in FIG. 2, where an additionallaser (1100) is added together with two beam splitters (2720)(2740) anda mirror (2600). This way the two laser beams are merged and followingthe same path. An additional detector (3100) is added and a beamsplitter (2700) may also be added.

A central aspect of the invention is to be able to use a cube corner(2200) to return the laser beam and then be able to focus the returnedlight onto one or more detectors (3000, 3100) non-co-axial design withreference to a light source system where the light source typically maybe a laser. To achieve this, a mirror assembly (2000) has been designed.The mirror assembly is comprising two mirrors, a first mirror (2100) inthe central part and a second larger mirror (2300) surrounding the firstmirror. These mirrors will be mounted so that there is an angle betweenthem. This angle is to be selected so that it fits the geometry of theoptical system i.e., the distance between the laser system and thedetector system with reference to their distance to the mirror assembly.The detector system comprises a single light sensitive detector (3000)in an instrument comprising one laser. In an instrument comprising twolasers the detector system comprises two detectors (3000, 3100) and abeam splitter (2700). In an instrument comprising one laser and a flatsurrounding mirror (2310) the detector system comprises a detector(3000) and a focusing lens (6000).

The central mirror (2100) will be flat if the laser beam divergence issuitable for use in the selected setup. The central mirror will beconvex or concave respectively if one wants to reduce or increase thelaser beam divergence. The larger, surrounding mirror can be flat(2310), spherical or parabolic (2300). In one first embodiment it isparabolic. The larger mirror (2300) will focus the beam onto thedetector system (3000). In another second embodiment the largersurrounding mirror (2310) will be flat as shown in FIG. 5 a. Thisembodiment comprises a lens (6000) that focuses the light onto thedetector (3000).

A system comprising two flat mirrors (2100, 2310) as described in FIGS.5 a and 5 b is easier to understand with regards to angle between thelaser beam or rays and the rays reaching the focusing lens (6000) andthe detector (3000). There is a direct correspondence between the anglebetween the two mirrors (2100, 2310) and angle between the optical axisof the light source system comprising the light source (1000) and thedetector system (6000, 3000).

To explain a central aspect of the invention it is assumed that the tiltof the mirror assembly (2000) has been adjusted to get maximum lightintensity onto the detector so that we are in a scenario as shown inFIG. 5 a. If the retro reflector is moved or rotated, the completeinstrument comprising the laser, mirror assembly, detector system etc.relatively to retro reflector the alignment will be lost and the lightintensity onto the detector will be reduced. If we as an example takethe setup shown in FIG. 5 a) and move the retro reflector somewhat upthe light intensity onto the detector will be reduced significantly. Themirror assembly is then adjusted to achieve the maximum light intensityonto the detector. We will then have a situation as described in FIG. 5b). In FIG. 5 b it can be seen that the retro reflector has been movedup and that the angle alpha of the mirror assembly has been reduced withan amount delta. However, the light is still focused onto the same spoton the detector. This is a central idea of this invention.

In a typical embodiment the flat surrounding mirror (2310) will bereplaced by an off-axis parabolic mirror (2300). However, the sameprinciples apply for the angle between the large mirror and the centralsmall mirror and their correspondence with the angle between the opticalaxis of the light source system and the optical axis of the detectorsystem. Using a parabolic mirror the focusing lens (6000) is not neededto focus light onto the detector. Systems using a parabolic mirror areshown in FIGS. 1, 2 and 3.

It is a requirement that the returned beam from the retro reflector hasa larger diameter or cross section than the size of small central mirrorso that there is sufficient light to be focused onto the detectorsystem.

Ideally the mirror assembly move or tilt around a point at the surfacein the centre of the small central mirror. This is possible to implementusing a gimbal like mechanical design to retain the mirror assembly.However, it is easier to implement an opto-mechanical solution where thepoint of movement is put a certain distance behind the surface of thecentral mirror as shown in FIGS. 1, 2 and 3. Such a solution will give asomewhat smaller adjustment range.

It should be emphasized that the term “comprises/comprising” when usedin this specification is taken to specify the presence of statedfeatures, integers, steps or components but does not preclude thepresence or addition of one or more other features, integers, steps,components or groups thereof.

BRIEF DESCRIPTION OF THE DRAWINGS

The above and further features of the invention are set forth withparticularity in the appended claims and together with advantagesthereof will become clearer from consideration of the following detaileddescription of an [exemplary] embodiment of the invention given withreference to the accompanying drawings.

The invention will be further described below in connection withexemplary embodiments which are schematically shown in the drawings,wherein:

FIG. 1 is illustrating the basic alignment part of the current inventionwith a laser (1000), a mirror assembly (2000), an external retroreflector (2200) and a detector (3000);

FIG. 2 is illustrating the invention when a second laser (1100) isintroduced together with beam splitters (2720)(2740) as well as a mirror(2700) and a second detector (3100);

FIG. 3 is illustrating the addition of means to check the integrity ofthe instrument during normal operation;

FIG. 4 a, b and c show a retro reflector (2200) mounted in a holder(2230) and with shades or beam blocking plates (2210, 2211).

FIGS. 5a and 5b shows a mirror assembly consisting of two flat mirrors(2100 and 2310) which are used for beam steering.

FIG. 6 shows one possible implementation of the alignment system thatcan be used to align the gas monitor by changing the pointing directionof the mirror assembly (2000). FIG. 6 a) shows a cross section of thealignment mechanics. It is actually the cross section A-A of FIG. 6 b)which shows the mirror assembly from the mirror side. FIG. 6 c) showsthe alignment system from one side. FIG. 6 d) shows the alignment systemfrom the rear side.

FIG. 7a shows the surrounding mirror surface (2300) and its optical axis(2350) without a hole for the central mirror.

FIG. 7b shows the central typically flat mirror (2100) and its opticalaxis (2150).

FIG. 7c shows the surrounding mirror (2300) with its central hole wherethe central typically flat mirror (2100) is placed.

FIG. 8 shows a retroreflector (2200) where substantially the centralpart (2240) of the reflective surfaces of the retroreflector (2200) hasbeen removed and replaced by a diffusor element (2250).

Note that the figures are not to scale.

DESCRIPTION OF REFERENCE SIGNS

The following reference numbers and signs refer to the drawings:

Reference number Description 1000 Light source, typically a laser 1100 Asecond laser with a different wavelength than the first laser 1200 Alaser for alignment, typically visible, possibly red 2000 Mirrorparabolous assembly 2050 Point or axis of rotation mirror parabolousassembly 2060 Push-screw in alignment system 2070 Pull-screw inalignment system 2100 Flat mirror reflecting divergent beam fromlaser(s) 2150 Optical axis of surrounding mirror 2200 Retro reflector,cube corner 2210 shade or beam blocking plate 2211 shade or beamblocking plate somewhat larger 2230 Holder for retro reflector 2240Central part of the retro reflector 2250 Diffuser element 2300 Parabolicsurface focusing returned light onto detector(s) 2310 Flat mirrorequivalent to parabolic mirror 2350 Optical axis of central mirror 2500Window of apparatur, tilted and wedged 2600 Mirror for reflecting mergedlaser ligth to the flat mirror 2100 2700 Beam splitter for splittinglight from two lasers onto two detector 2720 Beam splitter for includinga first laser 2740 Beam splitter for including a second laser 2810 Alens for focusing a reference signal from the first laser 2820 A lensfor focusing a reference signal from the second laser 2910 A span orreference cell for check of the first laser 2920 A span or referencecell for check of the second laser 3000 Light sensitive detector 3100 Asecond detector for detecting light from the second laser wavelength3200 A detector for check of the first laser 3300 A detector for checkof the second laser 4100 Divergent beam from laser 4200 Beam from laserreflected by flat mirror 4210 Beam from laser reflected by flat mirror,angle changed 2 delta 4300 Beam reflected from cube corner on its way toparabolic mirror 4310 Beam reflected from cube corner on its way to flatparabolic equivalent, angle changed 2 delta 4400 Focused beam fromparabolic mirror to detector 4410 Beam focused onto the first detector4420 Beam focused onto the second detector 4450 Beam reflected from flatmirror parabolic equivalent to focusing lens 4460 focused beam on itsway to the detector 5000 Target gas to be analysed 6000 Lens forfocusing light onto detector

DETAILED DESCRIPTION OF EMBODIMENTS

Various aspects of the disclosure are described more fully hereinafterwith reference to the accompanying drawings. This disclosure may,however, be embodied in many different forms and should not be construedas limited to any specific structure or function presented throughoutthis disclosure. Rather, these aspects are provided so that thisdisclosure will be thorough and complete, and will fully convey thescope of the disclosure to those skilled in the art. Based on theteachings herein one skilled in the art should appreciate that the scopeof the disclosure is intended to cover any aspect of the disclosuredisclosed herein, whether implemented independently of or combined withany other aspect of the disclosure. For example, an apparatus may beimplemented or a method may be practiced using any number of the aspectsset forth herein. In addition, the scope of the disclosure is intendedto cover such an apparatus or method which is practiced using otherstructure, functionality, or structure and functionality in addition toor other than the various aspects of the disclosure set forth herein. Itshould be understood that any aspect of the disclosure disclosed hereinmay be embodied by one or more elements of a claim.

The following disclosure focuses on examples of the present disclosureapplicable to gas monitoring by optical means. For example, this isadvantageous for long open path applications of gas monitoring. However,it will be appreciated that the description is not limited to thisapplication but may be applied to many other systems where optical gasdetection is performed.

In a first example, illustrated in FIG. 1, a gas monitoring system isshown with a moveable mirror assembly (2000) comprising a parabolicsurface (2300), said parabolic surface having a hole, in which anessentially flat mirror (2100) is mounted. Said mirror assembly can betilted in all directions using mechanics and motors or any otheravailable actuators. Actuator control is done by electronic componentswhich are controlled by a processing unit. Based on laser modulation andmeasurement of the detector signal the microprocessor can determine theoptimal alignment for the instrument, tune for maximum “smoke” i.e.,maximum signal.

The mirror assembly (2000) is designed so that when the laser (1000)emits light (4100) this light reaches the essentially flat mirror (2100)in the mirror assembly, the light reflected (4200) from said essentiallyflat mirror will reach the retro reflector (2200), and the lightreflected (4300) from the retro reflector hits the parabolic mirror(2300), the parabolic mirror focuses the light (4400) that finallyreaches the detector (3000). As long as the instrument is coarselyaligned and within the adjustable range, the internal alignment meanswill be able to align the instrument. In addition, the mirror assemblydesign assures that that laser light will follow the intended paths alsowhen alignment away from the centre position is required.

In another example, as illustrated in FIG. 2, the disclosure alsoenables multiple lasers to be included in the design, following the sameoptical paths and utilizing the same alignment means. An additionallaser (1100) is added together with two beam splitters (2720)(2740) anda mirror (2600). This way the two laser beams are merged and follow thesame path. An additional detector (3100) and a beam splitter (2700) arealso added. This beam splitter lets the light from the first laser(1000) through while the light from the second laser (1100) is reflectedand reaches the second detector (3100). The signals from the two sets oflasers and detectors can be processed independently to obtainmeasurements in two different wavelength ranges.

The light source system (1000, 1100) comprises the laser and beamforming optics. The light source system will in this application bereferred to as the “laser”. The beam forming optics will be designed andadjusted so that the laser beam (4100) has a suitable divergence for anactual installation and optical path length.

In the illustrated example, a visible laser (1200) with a collimatedbeam is also added so that the operator of the instrument can see wherethe instrument currently is pointing.

FIG. 2 is illustrating the invention when a second laser (1100) isintroduced together with beam splitters (2720)(2740) as well as a mirror(2700) and a second detector (3100). The optical design described inFIG. 1 is ideal when two or more lasers are present in one system likein FIG. 2 since both beams can be merged and go through the same opticsand this optics can also be aligned internally and automatically insidethe instrument housing. A visible laser for alignment (1200) can also beintroduced making it possible to see where the instrument is pointing.This laser has a collimated beam while the tuneable ones have adivergent beam;

In another example, as illustrated in FIG. 3, the disclosure allowsinclusion of verification means in the same optical design so that eachlaser can be checked continuously with regards to wavelength drift etc.Excess light from the beam splitters (2720)(2740) can be sent throughgas cells (2910)(2920) and onto detectors (3200)(3300). The condition ofthe laser can be checked using the spectral properties of the gas in thecell.

FIG. 3 is illustrating the addition of means to check the integrity ofthe instrument during normal operation. This can be used to check thatthe laser wavelength is within the correct range or to check calibrationusing an internal optical path. In the figure there is one cell ormodule for each laser typically comprising different gases, or the samegas mix containing gas(es) with absorption lines in the wavelengthranges for both lasers. Excess light from the laser(s) is emittedthrough the beam splitter(s) (2720)(2740) and is focused by the lens(es)(2810)(2820), this light goes through the gas cell(s) (2910)(2920) andreaches the detector(s) (3200)(3300). In cases where the gas to bemeasured are not normally present, the target gas can be present in thecell thus making it possible to check that the laser still is operatingin the correct wavelength range. A span check can also be done sincecalibration changes typically are due to changes in the laser output dueto long time drift or change.

In some examples, said essentially flat mirror (2100) is not preciselyflat, but instead has a curvature, in some examples to allow betterfocusing of the laser beam.

In some examples, said concave surface (2300) is not parabolical, butinstead has another curvature.

In some examples, a plurality of detectors is utilized not by the use ofbeam splitters, but by using combined or sandwiched detectors that aresensitive to the different wavelengths, or in some examples by othermeans of spectral separation.

In some examples, a single detector is used and the different laserwavelengths are separated by the use of time-multiplexing orfrequency-multiplexing techniques.

Some lasers are more sensitive to optical feedback than others. Thebasic design of this invention returns some of the light from the retroreflector to the small central mirror which in turn returns light to thelight source system. This feedback can disturb the laser so that moreoptical noise is generated or in the worst case make the lasernon-operational. This can be solved by inserting a shade or beamblocking plate (2210,2211) in the central part (2240) of the retroreflector (2200). The diameter of the shade can be adjusted to theoptical path length and beam divergence. The diameter can be optimisedfor a certain range of optical path lengths for a given beam divergenceand geometry of the collimating optics. Ideally the shade should blocklight from reaching the central mirror since this light will notcontribute to the signal on the detector, but could disturb the laser.

FIG. 4 a, b and c show a retro reflector (2200) mounted in a holder(2230) and with shades or beam blocking plates (2210, 2211). FIG. 4 bshows a somewhat larger shade (2211) than the shades (2210) shown inFIG. 4 a and c. As can be seen from FIG. 4 c the shade or beam blockingplate (2210) is tilted so that reflected light beams will be sent out ofthe optical path so that it will not reach the laser or end up on thedetector.

An additional embodiment for reducing light being reflected back to thelight source (1000) is to remove the central part (2240) of theretroreflector (2200) when the retroreflector (2200) is beingimplemented as a cube corner of reflective surfaces. This gives easiermaintenance than a beam blocking plate (2210) if cleaning of opticalsurfaces is required. An additional feature is to place a diffusorelement in the central part (2240) of the retroreflector (2200) toreduce optical noise and to reduce reflections from surfaces behind theretroreflector (2210). This is shown in FIG. 8.

The dimensions of the central area (2240) where the reflective surfaceis being removed will be adapted to actual distances and dimensions ofthe different components to avoid reflections back to the light source(1000), but at the same time give the best possible measurement signalfor the gas monitor.

One example of removing the central part (2240) of the retroreflector(2200) and at the same time creating a diffusor element is to sand blastor etch the central part of retroreflector (2200) to give a matte anddiffuse surface.

FIGS. 5a and 5b shows a mirror assembly consisting of two flat mirrors(2100 and 2310) which are used for beam steering. The central mirror(2100) directs the slightly divergent beam (4200 in FIGS. 5a and 4210 inFIG. 5b ) from the laser (1000) to a cube corner (2200). The cube corner(2200) is in both figures in the center of the beam (4200 in FIGS. 5aand 4210 in FIG. 5b ). The cube corner (2200) reflects the beam (4300 inFIGS. 5a and 4310 in FIG. 5b ) back towards the mirror assembly. Due toa slight divergence, some part of the reflected beam (4300 in FIGS. 5aand 4310 in FIG. 5b ) targets the large flat mirror (2310). Thereflected beam (4450) is directed towards the focusing lens (6000) whichfocuses the beam (4460) onto a photodiode (3000). In FIG. 5a the mirrorassembly is tilted with an angle α. In FIG. 5B the mirror assembly istilted with an angle α-δ. The direction of the reflected beam (4300 inFIG. 5a and 4310 in FIG. 5b ) from the central mirror (2100) is changedwith 2δ from FIG. 5a to FIG. 5b . The direction of the reflected beam(4300 in FIG. 5a and 4310 in FIG. 5b ) from the cube corner (2200) ontothe larger flat mirror (2310) is also changed with 2δ from FIG. 5a toFIG. 5b . Since the tilt angle of the large flat mirror (2310) ischanged with −δ from FIG. 5a to FIG. 5b , the direction of the reflectedbeam (4450) from the large flat mirror (2310) will be unchanged fromFIG. 5a to FIG. 5b . The focused beam (4460) from the lens (6000) willtherefore target the same spot at the photodiode (3000).

An instrument according to the invention must be aligned so that thelight beams travel from the laser (1000) to the central mirror (2100),from there through the window (2500), through the target gas (5000),then reaching the retro reflector (2200), then being reflected from theretro reflector back through the window to the surrounding mirror (2300)and finally being focused onto the detector (3000).

Adjusting the optical components so that the above is achieved will inthis application be referred to as “alignment”.

Alignment during manufacture of the instrument will typically berequired for the lasers (1000, 1100), the beam splitters (2720, 2740),mirror (2600), beam splitter (2700) in the detector section as well asfor the detectors (3000, 3100). Depending on the actual implementationof the mirror arrangement a lens arrangement in front of the detectorsmight additionally be needed. This lens arrangement might also needalignment.

Alignment in normal use by an end user will typically be done using acoarse alignment of the complete instrument and then only using themirror assembly (2000) for the final fine adjustment. Alignment innormal use will be done with using adjustment screws (2060, 2070) asshown on FIG. 6.

FIG. 6 shows one possible implementation of the alignment system thatcan be used to align the gas monitor by changing the pointing directionof the mirror assembly (2000). FIG. 6 a) shows a cross section of thealignment mechanics. It is actually the cross section A-A of FIG. 6 b)which shows the mirror assembly from the mirror side. FIG. 6 c) showsthe alignment system from one side. FIG. 6 d) shows the alignment systemfrom the rear side. The mirror assembly (2000) moves around the steelball (2050). The adjustment is done using push-screws (2060) and themovement in the other direction is arranged by having pull-screws whichcomprise a screw and a steel spring.

The alignment when the instrument is installed in the field could bedone using manual alignment means or using automatic or semi-automaticmeans. A full manual system can be based on adjustment screws tilting ormoving the mirror assembly (2000) around a “pivot” point (2050). Onepossible implementation is shown in FIG. 6.

FIG. 7 a shows the surrounding mirror surface (2300) and its opticalaxis (2350) without the hole for the central mirror. FIG. 7 b shows thecentral typically flat mirror (2100) and its optical axis (2150). FIG. 7c shows the surrounding mirror (2300) with is central hole where thecentral typically flat mirror (2100) is placed. The optical axis' (2150,2350) of both surfaces (2100, 2300) intersect in the same point whichshould be used as the pivot point for best performance of the system.

This intersection point is also preferably located at the surface of thecentral mirror (2100). Additionally the intersection point is thetheoretical point where the optical axis of the surrounding mirror(2300) intersects the surface of the surrounding mirror (2300) if therehad not been a hole in the centre of this mirror.

The optical axes (2150, 2350) of the central (2100) and the surroundingmirror (2300) intersect at an intersection point in the proximity (ofthe geometrical center) to the surface of the central mirror (2100).Preferably the distance between the intersection point and the surfaceis less than 10 mm, and more preferably the intersection point islocated at the surface of the central mirror (2100). The mirrorarrangement (2000)) can be tilted in any direction within a3-dimensional solid angle around a pivot point (2050), where the pivotpoint (2050) is located in the proximity of the intersection point. Thedistance between the pivot point (2050) and the intersection point ispreferably less than 20 mm, and more preferably the pivot point (2050)is located at the intersection point. Further, if the pivot andintersection point are not co-located, the pivot point (2050) ispreferably located behind the surface of the central mirror (2100).

The mirror arrangement can be tilted as one integral unit relative toother parts of the gas monitor system, in any direction within a3-dimensional solid angle, and thus providing alignment of the system byonly tilting the mirror arrangement.

An automated or semi-automated alignment system will be based onactuators having similar functions as the adjustment screws except thatno lock screws will be needed. Using at least one of the lasers and atleast one of the detectors including electronics and digitising unit theactuators will be used to scan over the possible range to find themaximum signal intensity. One possible scan strategy will be to start inthe centre and follow a spiral pattern outwards either a normal spiralor a square like spiral. Possible approaches are to stop at asufficiently high local maximum or to scan across the whole range tofind the global maximum. In a semi-automated mode the alignmentprocedure will be started by manual intervention while in the automatedmode the alignment procedure will start when the signal intensity isbelow a certain threshold for a specified time. Many other more complexcriteria for starting the alignment procedure are also possible.

Depending on implementation type the receiving optics will either be thecurved or typically parabolic mirror (2300) which focuses the light ontothe detector system. In case the surrounding mirror is flat (2310) thereceiving optics will comprise a focusing lens (6000) as well.

An instrument according the present invention will acquire data whichare a characteristic of the target gas. The instrument can also acquiredata which are the characteristic of the gas or air present in theoptical path inside the instrument and the gas or air in the opticalpaths outside the instrument, but not in the target gas. The completeinstrument can be purged with nitrogen to avoid contribution from oxygenin the air inside the instrument.

The instrument can also acquire data from temperature, pressure, flowvelocity and other sensors.

Based on the acquired data and predetermined knowledge and data thecontrol unit will calculate the concentration of one or more gases andpossibly the temperature (T) and/or pressure (p) based on spectroscopicdata.

The Control unit comprises means to control the instrument i.e.,temperature control, scan and modulate the laser, acquire data from thedetectors and other inputs (T, p, etc.). The control unit will also doother required “housekeeping” tasks for the instrument. As alreadymentioned the control unit will calculate gas concentrations and otherparameters. The control unit has and controls different input and outputunits (I/O) which are used to input other signals like T and p and tooutput results like the gas concentration(s). The control unit uses theI/O also for setup of the instrument as well as calibration and faultdiagnosis.

In the current application the mirror assembly (2000) is also referredto as a mirror arrangement since the central and surrounding mirrors arearranged with a certain angle in-between. The mirror assembly has apointing direction which can be defined with reference to either theoptical axis of the surrounding or the central mirror or both. Duringalignment the pointing direction of the mirror assembly will beadjusted.

The optical axis of a flat mirror will be the normal of the mirrorsurface. The normal which coincides with the optical axis of otherelements will be selected as the optical axis if applicable otherwisethe normal in the centre of the flat mirror will be selected. In thecurrent invention the term “retro reflector” will be used for alldevices or surfaces, which reflects at least some light back to theinstrument so that it can be detected by the detector system. A retroreflector can then be a cube corner, a reflective tape or any otherdevice or surface capable of returning some light to the instrument.Even indoor or outdoor objects or surfaces might work as retroreflectors, walls, rock, the ground might be used.

The laser is arranged to that the light reaches the central mirror, thecentral and surrounding mirrors as well as the detector system arearranged so that the light reaching the central mirror is sent in thedirection of a retro reflector and then sent back to the surroundingmirror and then to the detector system. Angles and positions can bearranged in correspondence with the examples given in FIG. 5.

The mirror assembly moves around the point or ball 2050. An arrangementwhere the mirror assembly slides on top of a curved surface with largerdiameter can also be possible. This would probably lead to a largerdistance between the surface of the central mirror and the point ofmovement and will lead to a smaller adjustment range.

An optional implementation of a dual laser system as shown in FIGS. 2and 3 can be made using a central mirror with two reflective surfaceswith an angle in-between. The first surface could be coated with acoating that reflects the 760 nm range while it transmits otherwavelengths The next surface, possibly the rear surface having adifferent angle, will reflect all light. This arrangement could make itpossible to have a laser and detector systems mounted differently fromthe examples shown in FIGS. 2 and 3. The laser and detector systemscould then be more independently mounted, dependent only on the anglesbetween the different surfaces of the central mirror.

One embodiment of the invention has a VCSEL laser (1100) around 760 nm,the beam entering a beam splitter (2740) reflecting typically 90% of thelight from the laser and transmitting some visible light from thealignment laser (1200). The DFB laser (1000) around 2.3 micro meteremits light to the beam splitter (2720) which reflects around 90% of thelight in the 2.3 micron range, this beam splitter also comprising a antireflective coating for the 760 nm range so that the light from the firstlaser (1100) will be transmitted. The mirror (2600) directs the light inthe direction of the central mirror (2100). Beam splitter (2720) alsotransmits some visible light for the alignment laser (1200).

Incoming light to the detector system will reach beam splitter (2700)which reflects light in the 760 nm range to the detector (3100). Thesame beam splitter has anti reflective coating optimised for the 2.3micron region and the light originating from the laser (1000) will endup on the detector (3000).

It is possible to insert a cell containing the gas CO in a cell betweenbeam splitter (2700) and detector (3000). This can be used for linetracking and span or verification check.

Gas cells (2910, 2920) can combined with detectors (3200, 3300) be usedfor line tracking and/or span or verification checks. All the mentionedcells can either be permanently mounted or inserted using an actuatorsystem. Without cells the zero setting can be checked. The cells can beeither flow through or sealed.

The current invention has the advantage that it allows more than onelaser to be included in the same optical path thus also allowing one gasmonitoring instrument to measure several gas components even thoughthese gases have absorption lines so far apart that they cannot bescanned using one single laser. A group of embodiments comprising twodifferent lasers operating in different wavelength ranges will betypical for the utilisation of this invention.

One example of this will be an instrument for combustion analysiscomprising a first laser operating in the 760 nm region for measurementof oxygen (O2) and comprising a second laser in the 2327 nm region formeasurement of carbon monoxide (CO). The laser operating in the 760 nmregion could even scan more than one oxygen line enabling themeasurement of the gas temperature using spectroscopic means. It couldalso scan across a close by NO2 line thus making it possible to measureO2, NO2 and temperature with the first laser. By selecting thewavelength range of the second laser so that it could scan a CO line, amethane (CH4) line and also two water vapour lines, the second lasercould make it possible to measure three more gases with the same gasmonitoring instrument as well as temperature using the two waterabsorption lines. It will then be possible to measure 6 components, 5gases and temperature, in one instrument which needs only one hole inthe stack or duct for in-situ operation.

In specific applications like a glass furnace where the temperature ofthe process is high and one wants to avoid connecting the analyserdirectly to the process ducts, temperature measurement using oxygenlines will not be applicable since the laser beam will go through boththe process and the air between the analyser and the process duct. Forsuch applications measuring temperature using the water vapour lines inthe 2300 nm region could be used instead of the oxygen lines in the 760nm region.

An instrument according to the current invention can accommodate a widerange of laser types some samples are, but are not limited to, VCSELlasers, DFB lasers, QCL and ICL lasers, Fabry-Perot lasers, as well asdifferent array types of lasers. These lasers could be operating in allwavelength ranges where lasers are available and where there arematching gas absorption lines. Any combinations of lasers and wavelengthranges are possible as long as the transmission through optical windows,lenses and beam splitter substrates are sufficient for operation.

The gas monitoring instrument of the current invention can be used indifferent configurations like, but not limited to, open path, crossstack using retro-reflector or in a one-flange solution using a probewith a built in retro-reflector. The one-flange probe solution couldalso comprise means to block particles from entering the optical path orbeam. This could allow operation in environments where the dust-load istoo high for operation of optical systems.

1. A gas monitor system for determining at least one characteristic of a target gas (5000), the gas monitor system comprising at least one light source (1000), the light source (1000) being arranged for emitting light in a wavelength range where the target gas (5000) has at least one absorption line, the system further comprising a retro reflector (2200) with reflective means, and a control unit, the gas monitor system being arranged for directing the light through the target gas (5000) to the retro reflector (2200) returning the light to a receiving optics, the system further comprising a detector system with at least one light sensitive detector for detecting the light, the detector arranged for providing a signal to be received by the control unit, the control unit arranged for controlling the gas monitor system and calculating the at least one characteristic of the gas, wherein the gas monitor system comprising a mirror arrangement (2000), the mirror arrangement (2000) comprising a central mirror (2100) and a surrounding mirror (2300) each with a surface, a geometrical center and an optical axis, where the central (2100) and the surrounding mirror (2300) are arranged with an offset angle between their optical axes (2150, 2350), where the optical axes (2150, 2350) of the central (2100) and the surrounding mirror (2300) intersect at an intersection point in the proximity of the geometrical center of the surface of the central mirror (2100), where the mirror arrangement (2000)) can be tilted in any direction within a 3-dimensional solid angle around a pivot point (2050), where the pivot point (2050) is located in the proximity of the intersection point, the central mirror (2100) being arranged for receiving light from the light source (1000) and directing light to the retro reflector (2200), the retro reflector (2200) arranged for returning the light to the surrounding mirror (2300), the surrounding mirror (2300) arranged for reflecting the light into the detector system.
 2. The gas monitor system according to claim 1, where the intersection point of the optical axes (2150, 2350) is located less than 10 mm from the geometrical center of the surface of the central mirror (2100).
 3. The gas monitor system according to claim 1, where the pivot point (2050) is located less than 20 mm from the intersection point of the optical axes (2150, 2350).
 4. The gas monitor system according to claim 1, where the intersection point of the optical axes (2150, 2350) and the pivot point (2050) are located at the geometrical center of the surface of the central mirror (2100).
 5. The gas monitor system according to claim 1, where the gas monitor system is arranged for forming beams, each beam having an axis, beam (4100) from a light source system comprising the light source (1000) to central mirror (2100), beam (4200) from central mirror (2100) to retro reflector (2200), beam (4300) from retro reflector (2200) to surrounding mirror (2300) and beam (4400) from surround mirror to detector system, and where the gas monitor system is arranged for the beams to and from the retro reflector (2200) to be substantially co-axial, and the axes of the beams to the central mirror (2100) from the light source system and from the surrounding mirror (2300) to the detector system to be non-coincident.
 6. The gas monitor system according to claim 5, where system is arranged such that twice the angle between the optical axis of the central mirror (2100) and the surrounding mirror (2300) substantially corresponds to the angle between the optical axis of the light source system and the detector system (3000).
 7. The gas monitor system according to claim 1, where the central mirror (2100) and surrounding mirror (2300) each comprises a surface for reflecting light, and the mirror arrangement (2000) is arranged such that the surface of the surrounding mirror (2300) surrounds the surface of the central mirror (2100).
 8. The gas monitor system according to claim 7, the surfaces of the central (2100) and surrounding mirror (2300) are further arranged such that the intersections point of the optical axis (2150, 2350) are located at in the optical center of the central mirror (2100).
 9. The gas monitor system according to claim 1, where the central mirror (2100) is one of the following forms: flat, parabolic, off-axis parabolic, and spherical, and the surrounding mirror (2300): flat, parabolic, off-axis parabolic, and spherical.
 10. The gas monitor system according to claim 1, where the detector system is located outside the beams (4200, 4300) between the mirror arrangement (2000) and the retro reflector (2200).
 11. The gas monitor system according to claim 1, where the light source (1000) is a laser of one of the following types VCSEL lasers, DFB lasers, QCL and ICL lasers, Fabry-Perot lasers, as well as different array types of lasers.
 12. The gas monitor system according to claim 1, where the retro reflector (2200) is one of the following types: cube corner, or a reflective tape.
 13. The gas monitor system according to claim 1, where the mirror arrangement (2000) is arranged for pointing the beam from the central mirror (2100) in a pointing direction mainly towards the retro reflector (2200), and where the gas monitor system comprises alignment means for adjusting the pointing direction of the mirror arrangement (2000).
 14. The gas monitor system according to claim 13, where the alignment means are arranged for providing the tilting of the mirror arrangement (2000) mainly around the pivot point (2050).
 15. The gas monitor system according to claim 13, where the pivot point (2050) is located in the proximity of the geometrical center of the central mirror (2100).
 16. The gas monitor system according to claim 13, where the pivot point (2050) is located behind the geometrical center of the central mirror (2100) in the proximity of the optical axis (2150) of the central mirror (2100).
 17. The system according to claim 13, where alignment means comprises means for automatically aligning said mirror assembly towards the retro reflector (2200) by moving said mirror assembly while monitoring a signal, and finding an optimal signal.
 18. The system according to claim 1, where the system comprises a visible light source (1200) arranged for sending a collimated beam of visible light substantially co-axially with the beam from the at least one light source (1000) to facilitate alignment of the system.
 19. The gas monitor system according to claim 1, where the system comprises a plurality of light sources (1000, 1100) operating at different wavelengths, each light source (1000, 1100) having a beam splitter for merging the light beams from the light sources (1000, 1100) to a common path; said beam splitters having spectral properties for the light from the light sources (1000, 1100) corresponding to each beam splitter to be essentially reflected, while light at wavelengths from other light sources (1000, 1100) is essentially transmitted.
 20. The system according to claim 1, comprising a plurality of light sensitive detectors and a plurality of beam splitters for separating the wavelengths from each light source (1000) to individual detectors.
 21. The system according to claim 19, where the system is arranged for time-multiplexing or a frequency-multiplexing to separate the wavelengths from each light source (1000).
 22. The system according to claim 19, where the system is arranged to let excess light from the beam splitters pass through at least one gas cell for each of the light sources (1000, 1100) and then onto at least one additional light sensitive detector for each of said light sources (1000, 1100); said at least one gas cell containing gas with absorption properties that suited to be used for self-calibration and to monitor the instrument integrity with regards to spectral operation points.
 23. System according to claim 1, where the retro reflector (2200) comprises a beam blocking plate (2211) arranged substantially symmetrically around a center axis of the retro reflector (2200) for blocking light from being reflected by the retro reflector (2200) via the central mirror (2300) back to the light source (1000).
 24. System according to claim 23, where the blocking plate (2211) is substantially formed like a circular disc with a diameter optimized for a range of optical path length and beam divergence.
 25. System according to claim 23, where the blocking plate (2211) is arranged in an angle tilted relative to the optical axis of the retro reflector (2200).
 26. System according to claim 1, where the retro reflector (2200) comprises a central part (2240) where substantially the reflective means have been removed to avoid laser light being reflected back via the central mirror (2100) to the light source (1000).
 27. System according to claim 26, where a diffuser element (2250) is placed in the central part (2240) of the retroreflector (2200) where the reflective means have been removed, the diffuser element (2250) reducing optical noise and reflections from surfaces behind the retroreflector (2200).
 28. System according to claim 27, the reflective means of the central part (2240) comprising a reflective surface being sand blasted or etched for substantially removing the reflective surface and making the diffuser element (2250).
 29. A method for determining at least one characteristic of a target gas (5000), comprising the following steps: emitting light in a range where the target gas (5000) has at least one absorption line in a beam from a light source (1000); reflecting the light by the central mirror (2100) through a sample of the target gas (5000) towards a retro reflector (2200); returning the light by the retro reflector (2200) towards a surrounding mirror (2300) surrounding the central mirror (1000); reflecting the light by the surrounding mirror (2300) towards a detector system; detecting the light by at least one detector comprised by a detector system; receiving a signal from the detector system and determining at least one characteristic of the gas by a control system. 